• Complementary interface formation is critical for all-back-contact electrodes

• UV-ozone increased the work function of NiOx and removed residual carbon on TiO2

• Annealing after UV-ozone reduced hydroxide or defect species in NiOx

• 2D models highlight the dependence of carrier collection on interface defect density



All-back-contact (ABC) architectures for perovskite photovoltaics represent untapped potential for higher efficiency and enhanced durability compared to conventional planar architectures. Interface engineering can be more complex in ABC designs, because both the electron and hole transport layers (ETLs/HTLs) are simultaneously exposed during processing. Herein, we fabricate ABC perovskite solar cells with a non-stabilized current-voltage scan power conversion efficiency >10% by developing complementary interface processing. UV-ozone exposure followed by annealing increases the work function and reduces the defect density of the NiOx HTL and removed contamination from the TiO2 ETL, which increases voltage and current collection. We measure the chemical composition of each transport layer interface using photoelectron spectroscopy and then use the resulting trends to inform a two-dimensional drift-diffusion model. The model suggests that further reduction of charged interface defect density, increase in the hole selective contact work function, and passivation of the front surface will enable >20% of ABC devices.

Download to read the full paper >

Paper originally published by Cell Reports Physical Science

Get your free solar quote today!

Get Quote or call us on (08) 9300 9324

We are local energy experts, providing residential solar power and commercial solar power solutions in Perth, Western Australia. We are a family owned and run business providing solar solutions (solar panels, solar hot water, solar battery storage, electric vehicle chargers and more), for both residential and commercial customers. We have been in operation for over 11 years and are trusted for our technical expertise, honesty, professionalism, aftercare support and consultative, friendly approach.

Useful links: